Solar energy is an easily accessible and promising renewable energy source that could solve the current energy crisis. Thermal energy storage systems incorporating Phase Change Materials (PCMs) are widely preferred owing to their immense energy storage capacity. The thermal energy storage (TES) potential of PCMs has been deeply explored for a wide range of applications, but not limited to solar/electrothermal energy storage, waste heat recovery, energy savings in building, and thermal regulations. The inherent shortcomings like leakage during phase transition, poor thermal conductivity hamper their extensive usage. Nevertheless, it has been addressed by their shape stabilization with porous materials and dispersing highly conductive nanoparticles. This review article focuses on different synthesis methods for medium-temperature form stable composites and a special focus is given on their thermal performance. Following mathematical evaluators (enthalpy efficiency, crystallization factor
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