do not drop off dead. >> something do not add up. >> could be murder. >> do you believe the possibility that your husband was poisoned? who could have wanted him dead? >> he was pretty angry. >> he was initially angry about everything else. >> angry enough to kill. >> was his new wife endangered, too? >> brace yourself because this killer was stone cold evil. >> wow, this is, this got me shaking. welcome to "dateline," frank rodriguez who dedicated himself to helping needy children. investigators had a challenge on their hands figuring out who would want frank dead. how he died was also a mystery. when they need to catch his killer. ♪♪ >> reporter: in this world we like to think that we can tell the difference between good and evil. sometimes evil puts on a mask when it comes to life. a love one, a friend, someone we think we can help. by the time we figure out we are wrong, it's too late. >> he was drawn to people that were broken. >> frank gave a lot and did a lot of good in his life until he ran across another soul who was not just troubled or broken but pure evil. >> frank grew up in rural illinois. >> he was joking. >> you know funny jokes and little tricks and things. >> prankster was the word i am going for. >> after high school, frank joined the navy he married a local girl. that line about the sea being a jealous mistress is true. >> his first wife was tired of him traveling, being gone six months at a time. after he got out, he was a lost soul, he didn't know what he wanted to do and she ended up leaving him. after the divorce, frank was at loose ends, different jobs and relationships. until he found first religion. >> is there is any questions? >> and then a place called angel gate academy. >> he just loved that job, he loved working with the kids. angel gig was run by california's central coast. it was a military academy, the city kids headed in the wrong direction, learned orders, discipline and respect. >> how was frank with the kids? >> he was awesome with the kids. january hallway was frank's supervisor and friend. >> if they were acting out, he would say things to get them to do the right thing. >> he kind of like use me as a bad guy. >> good cop/bad cop. >> reporter: as rewarding it was for frank to help his students learning skills for successful life, he found it thrilling to see these kids kayaking or camping or hang out by the ocean which many have not seen. it left him wanting kids of his own. i remember him talking a lot about him wanting to have kids, he wanted kids really bad. he wanted to start a family. >> he was big into god giving him signs. >> he called mom to tell her that he met this woman and she was his soul mate. our mom was excited. oh my goodness, she was so excited. frank met someone. her name was angelina morales. she was also in the military. he was a devoted christian as frank. they met in february and married in april. angelina had a nine-year-old daughter named autumn. instant family. i like frank, he was a really good guy and down to earth. >> and good for her. >> usually a guy in your position not crazy about the husband come after him. >> with frank, it was different. >> at the wedding, frank vowed to be a good husband and he made a promise to autumn to be a great step dad. then frank who loved working with kids was offered a teaching job in los angeles. frank's life seemed to be coming together the way he had always prayed it would, at least that's how it seemed. >> when was the last time you saw frank? >> i saw him the tuesday after labor day, 2000. >> reporter: frank wanted to earn some extra money, he agreed to chaperone a group of new students on their way to angel gate. he rode with them on a bus from l.a. where he met up with his old friend, chad. >> how did he look? >> he looked terrible. >> reporter: four days later, frank rodriguez was dead. >> frank rodriguez was living his dream but then suddenly he was dead. did his wife sense danger? coming up -- >> you are telling me your husband could be poisoned. >> who could do him harm? >> he looked at frank -- >> when "the devil in disguise" continues. 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(sha bop sha bop) ♪ ♪ ♪ alexa, play our favorite song again. ok. ♪ i only have eyes for you ♪ it was september of 2000, frank rodriguez was finally coming into his own. a new bride, a new family, a new job. then, at 3:00 a.m. after just 5 months of marriage, frank's new bride found him unconscious on their bedroom floor and called for help. it was too late. frank rodriguez was dead. his family was stunned. he had been a healthy man. >> my mother called me, she lost it and screaming and slammed the phone. it was horrifying. he was only 41. frank left behind a widow and a nine-year-old stepdaughter who whom frank became really close. >> she was devastated but also very confused. >> she was not the only one confuse ds. the coroner's office found no obvious cause of death, no heart attack or trauma. toxicology found a little viking in his system but not enough to kill anyone. his family was at a loss especially his wife angelina who seemed to be groping for answers, trying to make sense of what happened to frank. >> she called me everyday to talk about it. she thought he was poisoned and killed. >> the idea seeing on the face of it was crazy. >> homicide detectives were called in even though there were zero evidence of a homicide. >> any chance this is going to turn out not to be a murder and frank thought it's natural causes or food poisoning or something like that? >> absolutely. >> detective brian steinwad says his job was to keep moving forward. >> we were dependant on what the coroner's office was doing. in the meantime you can't stop investigating. >> in a few day after frank's death, they spoke with angelina about her suspicions. >> we were here because we understand, you have information or believe there is a possibility that your husband was poisoned. >> angelina had a lot to tell detective about frank's final day, about she thought what had happened to him and why. >> we are going to start from the beginning. >> angelina says after his trip on the bus, frank got sick. was what they both thought at first was a stomach flu. >> it was not like constant, it was every once half hour. but then frank got so sick that angelina took him to the er. the doctor says all frank needed was rest and fluids and he would get better. two days later frank was dead. angelina now told detectives she didn't believe it was a stomach flu at all. she thought something happened to frank on that trip to angel gate. >> he was feeling okay with you? >> yes. >> angelina told detectives she urged frank not to chaperone those community students and specifically not to go back to angel gate. >> you tell him before he went? >> oh yeah. >> we argued. i said please don't go. >> he was worried that frank who was so trusting would not be safe. >> i mean he looks good in everything, he thinks everybody can change. >> angelina says why she was afraid. it turns out when she and frank worked together at angel gate, they became involved of something dangerous. >> we were pray together and we were both very prophetic. we both recognized and knew of the situations. >> the situations? she and frank became convinced of a person working at angel gate was engaged in inappropriate behavior with some of the students. >> angelina says she reported the man to authorities. he now have a motive to hurt her or frank. >> this person had said if anybody jeopardize my job, i will kill them. he looked at frank and he went like this and -- pop, dead on. eye to eye. >> despite her fears, that night when frank returned from angel gate, he told her everything seemed fine. >> they were great. they hugged me and they said they missed me and somebody -- he didn't say who. he said somebody in the office -- now she wondered, was there something in that gatorade. did that friendly welcome hide something much more sinister. the man offered frank food and drink was the same man angelina accused that threatened frank months earlier. >> my instincts are usually real. >> sergeant hallway, frank east former boss and friend. >> coming up -- >> i can't even describe how angry i was. >> chad hallway from friend to suspect. >> did you say you put your gun to the head of the person who's doing is this? >> when "the devil in disguise" continues. lvvil in disguise" continues. trelegy for copd. ♪ birds flyin' high ♪ ♪ you know how i feel ♪ (coughing) ♪ breeze driftin' on by ♪ ♪ you know how i feel ♪ copd may have gotten you here, but you decide what's next. start a new day with trelegy. ♪ ...feelin' good ♪ no once-daily copd medicine has the power to treat copd in as many ways as trelegy. with three medicines in one inhaler, trelegy helps people breathe easier and improves lung function. it also helps prevent future flare-ups. trelegy won't replace a rescue inhaler for sudden breathing problems. tell your doctor if you have a heart condition or high blood pressure before taking it. do not take trelegy more than prescribed. trelegy may increase your risk of thrush, pneumonia, and osteoporosis. call your doctor if worsened breathing, chest pain, mouth or tongue swelling, problems urinating, vision changes, or eye pain occur. take a stand and start a new day with trelegy. ask your doctor about once-daily trelegy. and save at trelegy.com. we gave new zzzquil pure zzzs restorative herbal sleep ask your doctor about once-daily trelegy. to people who were tired of being tired. i've never slept like this before. i've never woken up like this before. crafted with clinically studied plant-based ingredients that work naturally with your body. for restorative sleep like never before. it's another day. and anything could happen. it could be the day you welcome 1,200 guests and all their devices. or it could be the day there's a cyberthreat. only comcast business' secure network solutions give you the power of sd-wan and advanced security integrated on our activecore platform so you can control your network from anywhere, anytime. it's network management redefined. every day in business is a big day. we'll keep you ready for what's next. comcast business powering possibilities. it was very hard for the funeral. angelina's daughter who was in the white house when frank died, said good-bye in a way only a child could. >> autumn put a teddy bear in frank's coffin. she was a sweet little girl. >> that last good-bye was a struggle for frank's family. >> it was very hard on mom. she did go into deep depression after that. >> as a people who loved him more, detectives with the los angeles sheriff department were trying to find answer. >> they drove 200 miles north in a small town of san lewis, to angel gate to check out angelina's unsettling story. she accused of chad hallway with misconduct with students. chad was furious with that and that may be the reason behind frank's unexplained death. >> they were asking us our opinion of who had access to frank. ronsan told police he did not know chad talked to frank. >> chad was besides himself, i never seen him that angry. >> chad was angry with ta ang sanitation. he expressed to some people he would like to deal harshly with who have done with it. >> he was angry about it. >> angry enough to kill. >> we don't know chad hallway very well yet. we get to know him. >> what detectives call getting to know you does not seem so friendly when you are a potential suspect. >> i was under the impression that before they talked to me, they were so convinced i did this. they came up and asked a lot of questions. >> detectives already learned something important. the misconduct allegations had been thoroughly investigated by law enforcement and found to be completely baseless. but the detectives also knew a false allegation could be a very good motive for murder. that's one of the worst things that a teacher or instructor can do to a kid. it's also one of the worst things to be accused of you didn't do it. >> that was probably the scariest thing. a lot of things happened in combat, i never in my life have been that scared. >> scared and he admitted angry. i was beyond mad. i can't even describe how angry i was. >> did you say you like to put your gun to the head of the person who was doing this to you and pull the trigger. . >> something to that effect. >> some where along the lines of you were the target of false allegations from the whief of a guy who's now dead and you were angry at the time of those fall allegations. >> nearly ruining your life over some allegations. that's enough for l of people and i guess it could be, yes. >> chad hallway insisted to detectives and us whatever threats he made out of anger and frustration that he would never go it through. >> when you said you want to take a gun and put it to the head of the person with ak accusations against you. you didn't know it was angelina. >> i didn't. >> once you thought it was angelina, you thought about putting a gun to her head? >> absolutely not. >> when angelina told detectives about the visit at angel gate never happened. >> did you offer frank a gatorade? >> no. >> someone was lying. >> the question was who? questi? >> coming up -- >> all i heard was ask them about antifreeze. who and what had killed frank? investigators have a secret mission for sergeant hallway. >> he said i am in. >> you better believe it. >> when "the devil in disguise" continues. in disguise" continues. . mind if i root through your trash? now get powerful relief with robitussin elderberry. and that's just basic wavy guy maintenance, right? next up, carvana. oh, boy. carvana just doesn't seem to understand how the test drive works. they give their customers seven days. and if they don't like it, they give 'em their money back. wait, they take the car back? that's crazy! what if it was driven by like a zookeeper? or a mud wrestler? or a guy who's on the outs with the missus and he just needs a place to sleep for seven days? yeah. 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a gentleman that worked there also some what of a cowboy and all of a sudden she showed up with a cowboy bumper sticker. >>. and all of a sudden she's a cowgirl. >> and she recognized that frank is a religious man. >> angelina was shopping pretty hard for a man. and would do what was necessary to get one. >> she was pretty much like a camillion. >> they learned after meeting her, frank became less close to my of his friends at angel gate. when the couple moves out, frank seemed to cut-off his own family. >> he called me on mother's day and said i can't talk long, she's monitoring my call. >> none of that fits the profile of a loving wife. after frank's death, she move up north and left behind some of frank's things. >> she took his dress shoes and some of his uniform stuff and medals and stuff like that that he had and they were all in trash can. >> she threw them away? >> the things the trash was shocking. things you would keep from your husband that you love. >> all that was curious, there was one thing above all others that made detectives suspect angelina's responsible of his death. the way angelina kept on bringing life insurance. >> how long after frank died called insurance company? >> roughly within eight hours. >> the same day? >> the same morning. >> well, insurance probably won't pay until the coroner says what the cause of death is. as the days went on and the coroner still did not rule. angelina grew more and more impatient. >> i have a question. >> do you guys get anything at all? >> angelina kept ongoing. >> they don't have anything yet. it takes time for this type of stuff. unless they know what they are looking for. detectives an opportunity. they needed the same thing angelina did for different reasons. >> we need cause of death. and she knows what the cause of death is. they thought angelina may be telling truth about one thing. that frank had been poison. they knew what frank easter had told them. something strange that angelina said to her. >> there are a lot of ways you can poison someone. we have a flower out here. >> only in warm climate in southern california, leaves and flowers are toxic but only deadly quality. angelina seems to know how to do that. >> she says you can make a tea or soup out of it. it's a poison. >> when we were riding in the car, she pointed out those are bushes. >> angelina and frank's backyard. now they wonder since angelina was so eager to get a death certificate and collect life insurance, what did you slip up and tell them that maybe the plant is what killed frank. >> they spoke with her again and again gathering evidence against frank's co-workers. >> we keep on asking her. >> it could be anything, the flowers on the road or could be -- >> flowers on the road? >> yeah, what the heck are those? they grow them in the middle of the highway. >> at this point she knows what it's. >> she's trying to get you to say it. >> she would rather have us say it and we have her say it. >> try as they might, they could not get angelina say the word. >> she kept on calling them about chad and one day delivered another clue straight to investigators. someone had call her she said and told her something big. >> okay, it was about maybe five or ten after 8:00. >> that morning? >> yes. >> i was on my way back from my daughter. i would get this call and it was blocked. they wanted to tell me what was going on because they had a lot of respect for frank but they could not tell me who they were because they know how hallway is, you need to know a conversation i had with holloway, they do try and track down and they can't pin me because -- >> they can't pin me? they started breaking up and all i heard them was ask them about antifreeze. >> but, naming a new poison was only one interesting detail in the information. angelina had said the anonymous informa was after 8:00 a.m. >> i got her phone records. >> yes. >> there had not been any call near in coming or out going to angelina's phone at that time. >> the -- she implicated herself. detectives went to see chad to talk about angelina. >> angelina rodriguez, that was the last person that i have ever wanted to see or hear her name or have anything to do with whatsoever. >> then the investigators to you, we want to help build al case against her and you said i am better believe it. >> coming up. detectives came up with a plan to trap angelina but angelina had a plan of her own. >> wow, this got me shaken. >> when "the devil in disguise" continues. devil in disguise" continues. hide my skin? 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frank rodriguez was killed by ethylene glycol. the key ingredient in antifreeze. >> they knew for sure frank had been murdered and how and they thought they knew who. not chad but angelina. # to make this case stick, they need a little more. they kept her talking. >> we befriended her and first thing she did was offered us coffee. we kicked at each other, oh no, we are good. >> from the beginning angelina had tried to cast suspicion on frank's friend and co-worker, chad holloway. >> chad she says was the killer but detectives didn't believe her but enlisted chad to help set up trap for her. >> the idea is what her? >> to see what kind of mistakes she makes. they asked chad to call angelina to listen in. >> now came his chance to return the favor. >> hello? >> angelina. >> yes. >> why did you tell police that i poison frank? >> who is this? >> angelina, how in the world -- the could ruin my life. >> at what woint when you say angelina you are going to ruin my life, which actually although it's maybe part of the script for that call. it's kind of true given what she tried to do to you before. >> inside i knew it's the other way around. you are not going to ruin my life. it's your life is going to be ruined because of this. >> you need to call the investigator. i am ending this conversation. >> okay, angelina. >> then within a minute of chad hanging up, angelina called cops and gave them quite a different version of the call. >> i got a phone call from holloway. >> he said detectives -- and i go spreading these things around. he says what are you talking about? i don't need to be talking to you. >> he says -- he says you better watch your back. >> okay, oh god. >> i am scared to death. >> angelina should have been scared of but the cop were all over to her on her lies. >> the previous phantom call about antifreeze. >> angelina still had not admitted anything, at least not to detectives. they found a good friend of angelina's. she told the cops months after the wedding, angelina was bored with frank and cheating on him. >> they were sitting around like girls do talking about killing their husbands, oh, you are joking and how they would do it. >> as girls probably all do. my wife is probably doing right now. >> the friend said angelina didn't want to divorce frank because he just bought life insurance. >> he was making milk for frank. >> angelina had no idea what the cops knew. she thought they were still investigaing chad and she was still happy to help them do that. >> for example, detectives told angelina they could not figure out how chad knew when frank was coming to angel gate. he would have had known when they told her so he could have the poison ready. >> a fax shows up. it was the roster for the day of frank's visit, frank's name was written in. >> this is a fax that came right from the sheriff's homicide. >> it was convenient. >> the fact did not include the sender's name. >> it was the cover sheet of the facts that was received anonymously. >> why is chance still -- free? chad never knew how hard angelina pushed cops to arrest him? >> this gotten me shaken. >> five months after her husband's death, police dropped in at angelina's house. >> good morning. >> how are you? >> angelina thinks their next stop will be chad's place. it won't. >> holloway could not do this. >> the next 35 minutes, they tried to get angelina to give it up. they lay out the facts. the only information, the only person that supplied any information that frank was poisoned was you. no one else knew that frank was poisoned. only you knew. >> in addition to that and antifreese. nobody in this entire investigation told us about anty freeze. >> they told her the poison was still in frank's stomach. >> within hours of his death, meaning angelina was the only one who could have given it to him. >> and detectives tell us that all along she thought she was playing them. they were playing her. >> this entire time we have everything you said and follow-up everything you have done and said. it's hard to remember all those lies. >> angelina told them they were wrong. >> can i get a glass of water? >> okay. >> are you arresting me? >> no. >> i didn't kill my husband. >> no! no! >> i swear i didn't kill my husband. >> we can prove that you did. >> angelina rodriguez may see deep but she had a few more punches left in her. just wait. i didn't kill my husband, i swear. >> coming up -- >> a secret plan from inside prison and another under cover sting. >> when "the devil in disguise" cons. continues. continues and also try alevex topical pain relief. the new sensodyne repair and protect with deep repair has the science to show that the toothpaste goes deep inside the exposed dentin to help repair sensitive teeth. my patients are able to have that quality of life back. i recommend sensodyne repair and protect with deep repair. ♪ ♪ ♪ (sha bop sha bop) ♪ ♪ are the stars out tonight? (sha bop sha bop) ♪ ♪ ♪ alexa, play our favorite song again. ok. ♪ i only have eyes for you ♪ where's mom? she said she would be home in time for the show. don't worry sweetie, she promised she'd be here for it. oh! nice shot! thanks! glad we have xfinity. with wifi speeds faster than a gig. me too. [claps] woah! look! [chuckles] mom is on tv! she's amazing! [screams and laughter] yeah! xfinity brought us together after all. get started with xfinity internet and ask about wifi speed fast than a gig. click, call or visit a store today. welcome back to "dateline." detectives continue to piece together. their investigation yielded answers and the question, could she have murdered before. >> here is the conclusion of "the devil in disguise." >> she was charged with the murder of her husband. >> you think that they made i look like a suicide, what are you are hearing is the mind of her speaking in jail, speaking through the air vet in solitary. >>. >> angelina apparently believes the statements of her friend about how angelina was bored with frank and wanted a life insurance pay out with the most damaging evidence against her. so it seems angelina made a decision to hire someone to get rid of her friend. >> this is angelina inside the county jail trying to set up a hit on palmera outside to keep her from testifying. >> correct. >> the inmate angelina was talking with turn her in and detectives were recording her conversations. >> if they get cyanide, that would be really quick. >> angelina made clear she helps with their children. >> everything is done for it. >> i would vlz done it for my kids. >> that's how much i love my kid. >> they won't take in kids but she got to go. >> that was what i was thinking. >> police told palmero what she was up to and asked for her help. >> we basically stage her death. the picture is pretty convincing. >> it was very convincing. they sent an under coverer cop posing as a bad guy to visit angelina in jail. >> something has happened to your friend. >> who? >> what? >>. >> huh? >> where did you get those from? >> you need to get back to your family. >> her initial response was oh my god, oh my god, i was only kidding. >> i was only kidding. >> shortly after, oh my god, i am ready to go home. >> she killed her husband and she tried to kill a witness against her. >> right. >> and anybody else? her baby. >> in the course of their investigation into frank's death. detectives found out in 1993, angelina's daughter chokedpacif. >> she collected life insurance on her 13 months old baby. detectives came to believe that alicia's death was no accident. >> absolutely. >> angelina says she did not kill her baby and she was never charged with that. >> she did stand trial for the murder of frank rodriguez, a prosecution expert testified that angelina poison him at least twice. >> first with coriander which made him sick and she was dosing himg with antifreese which was fatal. >> the jury found her guilty of first degree murder for financial gain but could not reach a verdict whether she tried to kill that witness. in the sentencing phase, judge allowed the jury to hear evidence for her daughter's death. >> you shall be put to death. >> even facing a death sentence, she seemed unfazed. >> she addressed the court but only admitted to some errors. >> i broke and made a few terrible mistakes which i regret very much. we all make mistakes, i just picked the wrong time to make mine. murder is not one on that list. >> frank rodriguez thought angelina was the god fearing woman of his dreams. he was wrong. >> tom ford she was a nurturing mother who'll protect their daughter. he'll never know for sure. chad holloway understands he knows how close pure evil came to him. he says he let it go with the gratitude that unlike his friend, frank, he at least survived with his reputation and life intact. >> people need to know how evil angelina was. how many lives she ruined to try to get a little bit of money. she was not going to stop at nothing until she got what she wants. i want her to know that she didn't ruin me at all. >> in the bible near war that satan disguises himself as an an anl of life. >> that's all for this edition of "dateline," i am natalie morales. thank you for watching. >> i am craig melvin. >> i am natalie morales, this is "dateline." >> something is not right. >> i just flipped out. i lost it. >> we could not understand how anybody would want to murder him. he looked like he was sleeping but except for the bullet hole. >> his head was on the pillow and his entire upper body was tucked in. the first guess was suicide. >> this was a

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