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(a) Schematic structure of polarized light detector. (b) Photoconductivity parallel and perpendicular to the interface. (c) Photoconductivity anisotropy versus excitation power. (d) Angle-resolved photocurrent as a function of polarization angle measured at 405 nm under zero bias. (e) Experimental polarization ratios of some reported polarized light detectors. (f) Angle-dependent photocurrent of the present device measured at different temperature.
CREDIT
@Science China Press
Abstract:
Polarization-sensitive photodetectors, based on anisotropic semiconductors, have exhibited wide advantages in specialized applications, such as astronomy, remote sensing, and polarization-division multiplexing. For the active layer of polarization-sensitive photodetectors, recent researches focus on two-dimensional (2D) organic-inorganic hybrid perovskites, where inorganic slabs and organic spacer
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IMAGE: (a) Schematic structure of polarized light detector. (b) Photoconductivity parallel and perpendicular to the interface. (c) Photoconductivity anisotropy versus excitation power. (d) Angle-resolved photocurrent as a function of polarization angle. view more
Credit: @Science China Press
Polarization-sensitive photodetectors, based on anisotropic semiconductors, have exhibited wide advantages in specialized applications, such as astronomy, remote sensing, and polarization-division multiplexing. For the active layer of polarization-sensitive photodetectors, recent researches focus on two-dimensional (2D) organic-inorganic hybrid perovskites, where inorganic slabs and organic spacers are alternatively arranged in parallel layered structures. Compared with inorganic 2D materials, importantly, the solution accessibility of hybrid perovskites makes it possible to obtain their large crystals at low cost, offering exciting opportunities to incorporate crystal out-
Credit: @Science China Press
Metallacages prepared via coordination-driven self-assembly have received extensive attention because of their three-dimensional layout and cavity-cored nature. The construction of light-emitting materials employing metallacages as a platform has also gained significant interest due to their good modularity in photophysical properties, which bring emerging applications in fields as diverse as sensing, biomedicine, and catalysis.
However, the luminescence efficiency of conventional luminophores significantly decreases in the aggregate state because they encounter unfavorable aggregation-caused quenching (ACQ). Therefore, it was quite a challenge to fabricate light-emitting metallacages with high luminescence efficiency in various physical states.
In 2001, Tang s group discovered aggregation-induced emission (AIE) phenomenon that some nonluminous or weakly emissive materials in molecular state are highly emissive in aggregate state. The underlying mecha