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Chemists reconsider the impact of through-space effects


By Peter DaBell2021-04-07T13:21:00+01:00
Researchers in Israel investigating the reactivity of distonic radical ions have shown that through-space interactions have a far greater effect on reactivity than previously thought.
The team, led by Thijs Stuyver and Sason Shaik, from the Hebrew University in Jerusalem, carried out a computational study on the H-abstraction reactivity of a set of distonic phenyl radicals. Distonic radical ions are a class of radical ions in which the charge and radical are formally separated by two or more atoms. In the radicals studied by Shaik and co-workers, the charged substituent is chemically inert and the radical is contained within the aromatic ring, at either the para-, meta- or ortho-position to the substituent. ....

Israel General , United Kingdom , Hebrew University , City Of , Sason Shaik , Steven Wheeler , Thijs Stuyver , Rebecca Burns , University Of Edinburgh , University Of Georgia , இஸ்ரேல் ஜநரல் , ஒன்றுபட்டது கிஂக்டம் , ஹீப்ரு பல்கலைக்கழகம் , நகரம் ஆஃப் , சசொன் ஷேக் , ஸ்டீவன் சக்கர வாகனம் , ரிபேக்க தீக்காயங்கள் , பல்கலைக்கழகம் ஆஃப் எடின்பர்க் , பல்கலைக்கழகம் ஆஃப் ஜார்ஜியா ,