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The rapidly advancing energy storage performance of dielectric ceramics capacitors has garnered significant interest for applications in fast charge/discharge and high-power electronic techniques. Exploring the exceptional electrical properties in harsh environments can further promote their practical applications. Defect carriers can be excited under luminance irradiation, thereby leading to degradation of energy storage performance. Herein, a synergic optimization strategy is proposed to enhance energy storage properties and luminance resistance of (K0.5Na0.5)NbO3-base (KNN) ceramics. First, the introduction of Bi(Zn0.5Ti0.5)O3 solid solution and La3+ ions disrupts the long-range polar orders and enhances super paraelectric relaxation characteristics. Additionally, doping La3+ ions can increase the band gap and reduce oxygen vacancy concentration, resulting in excellent luminance resistance. Finally, the viscous polymer process is employed to suppress the grain growth and promote che ....
Antimony (Sb)-based anode materials are feasible candidates for sodium-ion batteries (SIBs) due to their high theoretical specific capacity and excellent electrical conductivity. However, they still suffer from volume distortion, structural collapse, and ionic conduction interruption upon cycling. Herein, a hierarchical array-like nanofiber structure was designed to address these limitations by combining architecture engineering and anion tuning strategy, in which SbPO4−x with oxygen vacancy nanosheet arrays are anchored on the surface of interwoven carbon nanofibers (SbPO4−x@CNFs). In particular, bulky PO43− anions mitigate the large volume distortion and generate Na3PO4 with high ionic conductivity, collectively improving cyclic stability and ionic transport efficiency. The abundant oxygen vacancies substantially boost the intrinsic electronic conductivity of SbPO4, further accelerating the reaction dynamics. In addition, hierarchical fibrous structures provide abundant active ....
In contrast to conventional oxidation techniques, tribocatalysis degradation of organics has gained much attention in recent years due to its mild requirement and low amount of energy needed. Therefore, we prepared Ba1.4Sr3.6NdNb7Ti3O30 (BSNNT) ferroelectric nanopowder by a solid-phase synthesis method and further investigated the effects of oxygen vacancies and heterojunctions on the tribocatalysis effect. The results showed that the introduction of oxygen vacancies not only reduced the valence electron potential required for the reaction but also greatly reduced the combination of electrons and holes. The efficiency of degradation of RhB by oxygen vacancy-rich BSNNT can reach 97 % after 2 h. Furthermore, the BSNNT-N2/CN-2 (BN2/CN-2) Z-type heterojunction achieves a tribocatalytic enhancement with 98.2 % RhB degradation in 2 h, which is attributed to the built-in electric field of ferroelectric materials and the appropriate band gap matching between g-C3N4 (CN) and BSNNT-N2 (BN2), fac ....
Photocatalytic CO2 reduction into valuable fuel and chemical production has been regarded as a prospective strategy for tackling with the issues of the increasing of greenhouse gases and shortage of sustainable energy. A composite photocatalysis system employing a semiconductor enriched with oxygen vacancy and coupled with metallic cocatalyst can facilitate charge separation and transfer electrons. In this work, mesoporous TiO2 and titanium-based perovskite oxides (BaTiO3 and SrTiO3) nanoparticle assembly incorporated with abundant oxygen vacancy and copper particles have been successfully synthesized for CO2 photoreduction. As an example, the TiO2 decorated with different amounts of Cu particles has an impact on photocatalytic CO2 reduction into CH4 and CO. Particularly, the optimal TiO2/Cu-0.1 exhibits nearly 13.5 times higher CH4 yield (22.27 μmol g−1 h−1) than that of pristine TiO2 (1.65 μmol g−1 h−1). The as-obtained BaTiO3/Cu-0.1 and SrTiO3/Cu-0.1 also show enhanced CH4 ....
Photovoltaic technology has been a research hotspot in the field of renewable and clean solar energy. More recently, the ferroelectric photovoltaic effect (FEPV) of BiFeO3 has attracted much attention, since it could obtain a giant open-circuit voltage (VOC) far beyond its bandgap and possibly break through the energy conversion limit of traditional solar cells. However, there has been controversy about the origin and the mechanism of FEPV in BiFeO3. In this work, (Pr, Ni) co-doped BiFeO3 film photovoltaic devices were well constructed and the intrinsic mechanism of the photovoltaic effect was comprehensively investigated. The results and analysis suggested that oxygen vacancies play significant roles on the photovoltaic effect of BiFeO3. Oxygen vacancies not only introduce impurity band as an intermediate band among the band gap of ferroelectric semiconductor to enhance the photocurrent, but also restructure the energy band of Schottky barrier at the interfaces through their electromi ....