shortly after that cabinet call, we saw in person, arriving on foot, john healey, the shadow defence secretary labour and also sir lindsay hoyle, the leader of the commons, arriving in 70 whitehall, which is the cabinet office that adjoins downing street and that the connecting corridors all lead through as if it is effectively one building. we also saw the foreign secretary, lord cameron, going into downing street. the expectation in situations like this, when time allows comets that senior opposition figures such as keir starmer, who we think has probablyjoined a call to be briefed as well, as well as the defence secretary and the house of commons speaker, would be briefed, where time to allow and it would appear in this instance that there is time because, as we understand it, no military strikes have happened as yet. the uk government always has the capacity to respond without consulting either the opposition or wider parliament, but convention would normally point in the
In this work, we described a remote desymmetrization reaction in which cesium carboxylate, in the presence of bisguanidinium as catalyst, was added to (cis)-α,α′-dibromocyclohexanone to access 6-oxocyclohex-1-enyl ester via a 1,2-acyl shift in a highly enantioselective fashion. In this process, the carboxylate initiated a nucleophilic attack, and then a keto-enol tautomerism led to a 1,2-acyl shift to the neighboring alcohol. Key intermediates were isolated and determined using single-crystal X-ray crystallography. The remote desymmetrization that includes stepwise SN2 and intramolecular acyl transfer was proposed and was further supported using computational studies. Finally, it was successfully applied to a tropinone derivative, realizing carbonyl chain walking efficiently.
Toyota apologized on Wednesday for an incident involving the fraudulent certification of its diesel engines that resulted in a corrective order from Japan's…
east, getting further down this ladder of warfare. so of course, the americans are not going to want to come in themselves and make things even worse across the region. but as one of your last guests were saying, they can t afford not to respond, given the nature of what has been going on. again, patrick ryder at the pentagon was describing the forces there as a highway patrol. he said, but if maritime shipping is being continuously attacked by the houthis, he said they will shoot first and ask questions later when it comes to repelling those particular attacks, so in their view, they have to be seen to respond to this, but they are going to need and want to calibrate it, if this is going to be an attack on some kind of land infrastructure, whether that be coastal radar or missile storage or whatever, they re going to want to try and calibrate it so it creates deterrence, but without making the fighting even worse, but already today we ve had
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