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Touched by Light: Photoexcited Stannyl Anions Are Great for Producing Organotin Compounds


Published: May 14, 2021
Scientists at Tokyo Institute of Technology developed a new strategy for producing a wide range of organotin compounds, which are the building blocks of many organic synthesis methods. Their approach is based on the photoexcitation of stannyl anions, which alters their electronic state and increases their selectivity and reactivity to form useful compounds. This protocol will be helpful for the efficient synthesis of many bioactive products, novel drugs, and functional materials.
Organotin compounds, also known as stannanes, are made of tin (Sn), hydrocarbons, and sometimes other elements like nitrogen and oxygen. During the 1970s, stannanes rapidly took the spotlight as building blocks in the field of organic synthesis mainly because of their use as reagents in the Stille reaction, which remains essential for chemists to combine various organic molecules. ....

United States , Chao Wang , Ken Tanaka , Kyoka Sakamoto , Masanobu Uchiyama , Kazunori Miyamoto , Yuki Nagashima , Shinshu University , Scientists At Tokyo Institute Of Technology , Chemical Technology , School Of Pharmaceutical Sciences , Tokyo Institute Of Technology , Cluster For Pioneering Research , Department Of Chemical Science , Journal Of The American Chemical Society , Information On School Of Materials , University Of Tokyo , School Of Materials , Research Initiative For Supra , Tokyo Institute , New Type , American Chemical , Assistant Professor Yuki Nagashima , American Chemical Society , Pharmaceutical Sciences , Chemical Science ,