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"Novel titanium vanadate with superior Na<sup>+</sup> transport kinetic" by Dan Lv, Liehao Wei et al.

Sodium-ion batteries (SIBs) hold great promise for large-scale energy storage in the post-lithium-ion battery era due to their high rate performance and long lifespan, although their sluggish Na+ transformation kinetics still require improvement. Encouraged by the excellent electrochemical performance of titanium-based anode materials, here, we present a novel titanium vanadate@carbon (TVO@C) material as anode for SIBs. Our TVO@C material is synthesized via a facile coprecipitation method, with the following annealing process in an acetylene atomosphere. The opened ion channel and the oxygen vacancies within TVO@C facilitate the diffusion of Na+ ions, reducing their diffusion barrier. Thus, an ultrahigh rate of 100 A g−1 and long life of 10,000 cycles have been achieved. Furthermore, the TVO@C electrode exhibits stable performance, not only at room temperature, but also at temperatures as low as −20 °C. The TVO@C||Na3V2(PO4)3@C full cells have also achieved stable discharge/charge ....

High Rate , Sodium Ion Batteries , Itanium Vanadate ,

"Advancing Li3VO4 as a high-performance anode material for use in lithi" by Yu Sheng Hsiao, Jen Hsien Huang et al.

Li3VO4 (LVO) is a promising anode material for use in Li-ion batteries (LIBs) owing to its safe discharge plateau and high capacity. However, its moderate Li+-diffusion coefficient and low electrical conductivity pose challenges to its widespread use in the LIB industry. In this study, hexavalent tungsten ions (W6+) were introduced to boost electrochemical kinetics, and W6+-doped LVO microspheres were successfully prepared using a spray-drying approach. Density functional theory (DFT) calculations reveal that the enhanced electronic conductivity and improved oxygen lattice following W6+ doping is possibly due to the development of a mid-gap state positioned above the valence band maximum. The doped LVO displayed excellent electrochemical performance, including a superior rate capability (288.9 mAh/g at 10C) and remarkable cycling stability (capacity fading of only 8.6 % over 200 cycles at 6C), which is ascribable to improved electrical conductivity and Li+ insertion/extraction. In addi ....

I Vo 3 4 , Lithium Ion Battery , Lithium Ion Capacitor ,