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Dark Blend, Vanilla, and Caramel. Although, the Dark Blend and Vanilla offers zero-sugar options - so you ll be seeing 5 total Coca-Cola with Coffee on the shelves. And as of Monday this week, you might already be seeing them. A 12-ounce can of this stuff has 69 milligrams of caffeine. A 12-ounce can of Coca-Cola has 34 milligrams of caffeine. While, an average cup of coffee has 95 mg of caffeine. Pick. your. poison. Need a 2 o clock pick-me-up? Well. WATER is actually pretty good for ya, but as the old adage goes, you can have your coke annnnd coffee t . wait I think I messed that up. ....