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"Conversion mechanism of sulfur in room-temperature sodium-sulfur batte" by Fan Jin, Ruijie Wang et al.

Room temperature sodium-sulfur batteries have attracted considerable interest due to their remarkable cost-effectiveness and specific capacity. However, due to the limited comprehension of its conversion mechanism, the decrease in sulfur cathode capacity in carbonate electrolytes is usually loosely attributed to the shuttle effect, which is well known in lithium-sulfur batteries that work in ether-based electrolytes. This work proposes a complete sulfur reaction mechanism in which the confined space is very important by combining the results from the theoretical calculations and electrochemical characterization. Specifically, crystal sulfur outside the pores is reduced to polysulfides, leading to irreversible reactions with carbonate solvents. Meanwhile, amorphous sulfur within the narrow pores undergoes an activation process during the first discharge and experiences a reversible conversion in subsequent cycles through a two-step solid-state reaction. Furthermore, the discharge/charge ....

Confined Space , Onversion Mechanism , Room Temperature Sodium Sulfur Batteries , Sulfur Cathode ,

Norfolk Fire-Rescue saves baby ducks from storm sewer

Norfolk Fire-Rescue responded to a rescue situation that was everything it was quacked up to be. ....

Norfolk Animal Control , Norfolk Fire Rescue , Fire Rescue , Rescue Situation , Confined Space ,