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High energy storage batteries for EVs need high capacity battery cathodes. New lithium-excess magnesium-rich cathodes are expected to replace existing nickel-rich cathodes but understanding how the magnesium and oxygen accommodate charge storage at high voltages is critical for their successful adaption. Research led by WMG, University of Warwick in collaboration with US researchers employed a range of X-ray studies to determine that the oxygen ions are facilitating the charge storage rather than the magnesium ions.