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Researchers report first direct observation of anionic redox in a lithium-rich battery material

Conventional Li-ion batteries work by cationic redox, when a metal ion changes its oxidation state as lithium is inserted or removed. Within this insertion framework, only one lithium-ion can be stored per metal ion. Lithium-rich cathodes, however, can store much more. Researchers attribute this to the anionic redox mechanism in this.

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