Photocatalytic water splitting is a promising strategy to produce hydrogen as a sustainable and clean energy carrier, based on abundant solar energy and semiconductor photocatalysts, and it has received extensive research and discussion over the past several decades. It is challenging, however, to achieve an efficient solar-to-hydrogen evolution process with a single particulate photocatalyst due to the weak solar spectrum harvest and the rapid recombination of photogenerated electron-hole pairs during the photocatalysis reaction. Combining semiconductors to create different co-catalysts presents a viable solution to the above issues. Recently, semiconductor photocatalysts modified by different transition metal sulfide-based co-catalysts with designed functions, especially in light absorption enhancement and charge-carrier-separation efficiency promotion, have attracted much attention. As continued breakthroughs have been made in the preparation, modification, and solar-to-hydrogen evo