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New Metal-Organic Frameworks Reduce CO2 to Formate

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Novel tin-based metal–organic frameworks for

Researchers from Tokyo Tech have developed a tin-based metal–organic framework (MOF) that can photocatalytically reduce carbon dioxide (CO2) into formate under visible light. The tin-based MOF exhibited a high apparent quantum yield of 9.8% and carried out extremely selective photoreduction without needing an additional photosensitizer. This could prove extremely useful, as currently, most metal complexes for reducing CO2 to useful chemicals utilize expensive, rare and precious metals.

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