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The development of large scale energy storage systems (ESSs) aimed at application with renewable electricity sources and in smart grids is expected to address energy shortage and environmental issues. Sodium ion batteries (SIBs) exhibit remarkable potential for satisfying the raw material supply and economic requirements of large scale ESSs because of the high richness and accessibility of sodium reserves. High stability of electrodes during cycling means long service life for energy storage, which is important for large scale ESSs to reduce the cost s generated by exchange or maintenance processes. Using low cost and abundant elements in cathodes with long cycling stability is preferable for lowering expenses on cathodes because it is vital for large scale ESSs to cut costs resulting from manufacture, exchange, and maintenance operations. Organic electroactive compounds hold great potential to act as cathode materials for SIBs because of their environmental friendliness, sustainabilit

Sodium ion batteriesCathode materialsEnergy storage mechanismPrussian blue analoguesNorganic materials