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Rotaxanes are interlocked molecular structures with a linear ‘axle’ molecule penetrating one or more cyclic ‘wheel’ molecules. Bulky groups at the end of the axle prevent the wheels from coming of .

Multicyclic polydimethylsiloxaneToshifumi satohAngewandte chemie international editionSilicone networkHokkaido universityProfessor toshifumi satohHigh molecular weight axleAngewandte chemie internationalAcro rotaxanesPolymer chemistry