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Earlier that day, his girlfriend and model Madeline Holtznagel, 24, appeared forlorn as she was spotted walking through Sydney's Double Bay.
She glanced repeatedly at her phone during the walk, wearing tiny black shorts and a P.E Nation jumper.
Back home: After jetting into the state's capital on a private jet, the businessman jumped into a car with the brunette
Chatting away: The pub baron chatted to the female while the chauffeur placed his bags into a blue Royce Rolls
Waiting game: The brunette was spotted standing nearby as their bags were placed into a car
Daily Mail Australia has contacted Hemmes and Holtznagel for comment. It is understood that he and the brunette are just friends.