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In equilibrium

 E-Mail Organometallic reagents are essential tools in synthetic chemistry. They work even better and more effectively in combination with alkali alkoxides. The exact nature of this effect has never been well understood. A team based in Switzerland has now performed a detailed study of the mechanism of reaction of aryl bromides with organo-magnesium reagents and lithium alkoxides. As reported in the journal Angewandte Chemie, a complex equilibrium of bimetallic intermediates plays a key role. Substituted aromatic ring systems are an important class of building block for the synthesis of many products, including pharmaceuticals, agrochemicals, and natural substances. However, the required functional side groups cannot generally be hooked onto the ring systems in a simple way. A widely employed method uses a detour through a halogen/metal exchange. First, a halogen atom, such as bromine, is attached to the desired position on the ring system. With the use of special organometallic

تعيين محمد خضر نائبًا لرئيس جامعة الأزهر لفرع البنات

تعيين محمد خضر نائبًا لرئيس جامعة الأزهر لفرع البنات
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Bucknell Astronomers Discover Binary Planetary System

Bucknell Astronomers Discover Binary Planetary System January 21, 2021 by Mike Ferlazzo An artist s composition of the two brown dwarfs Oph 98B in purple in the foreground and Oph 98A in red in the background. Rendering by Thibaut Roger Tags Using NASA s Hubble Space Telescope, Bucknell physics & astronomy Professor Katelyn Allers and postdoctoral researcher Blake Pantoja have observed an astronomical anomaly few have encountered before. They were part of an international research team that has discovered a new binary planetary system 450 light-years away from Earth composed of two brown dwarfs of differing masses orbiting around each other from a strikingly wide distance.

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