At Centro Deportivo Wanda, the hosts made a false start to the encounter as Iina Salmi played Candela Andujar through to hand the visitors a shock lead after 22 minutes of action.
Atletico, however, bounced back into the mix when Amanda Sampedro set up Ludmila to level eight minutes later before the duo combined well to gain the lead on the brink of half time.
After the restart, the hosts continued to preserve their narrow lead until Maria Jimenez gifted them a third of the match four minutes after Ajibade was brought on for Ajara Nchout in the 75th minute.
Eight minutes from full time, Sampedro grabbed her hat-trick of assists when she teed up the Nigerian to score her maiden Atletico goal to guarantee her side s return to winning ways, at home.